Multiwalled Nanotubes: Their Formation by Irradiating Graphite with High Doses of Electrons

We report the production of carbon nanotubes by high dose of electron irradiation. The irradiation was performed with a 2 MeV Van de Graaff accelerator, while the irradiation conditions were the following: voltage 1.3 MeV, current 5 µA, dose rate 25 kGy/min, and total dosage 1000 kGy. The samples were analyzed in a high-resolution transmission electron microscope. The main features observed on the samples, were huge nanotubes of several nanometer long and few nanometer wide, which are capped at one end. It is good to point out, that at this level of irradiation, we were not able to find either onion-like or particle structures throughout the material, as it is usual in similar hexagonal structures. This behavior could be attributed to the level of irradiation used to create the nanotubes under investigation.     

超低渗广谱油层保护技术在板深51区块的应用

板深51区块存在压力敏感地层，在非目的层井段存在大段高渗低压砂岩，而目的层又属于高压低渗地层，属于难采油气田。室内进行的砂床滤失量、砂床封堵带承压能力、岩心封堵带的承压能力及油气层保护效果实验表明，在超低渗钻井液中增加固相含量，能够提高超低渗透膜结构强度，提高地层承压能力，降低砂床侵入深度，增强保护油气层效果，而且有选择性地增加有用固相效果更佳。基于这一理论，研究成功了超低渗广谱屏蔽暂堵油层保护技术，并在板深51区块长22—15井和长23—17K井进行了试验应用。该技术的关键是依据地层特性确定复配暂堵剂。长22-15井和长23-17K井射孔后未经过压裂、酸化、排液处理，获自喷高产，尤其是长22-15井形成自喷油流，创油田单井试采产量最高记录。应用结果表明，超低渗广谱保护油气层钻井液技术封堵隔层的承压能力强，很大程度地提高了漏失层的承压能力和破裂压力，较好地解决了含多套压力层系长裸眼段钻井过程中发生的漏失、井喷、卡钻、油气层保护等技术难题。     

高功率激光系统通过空间滤波和中继成像抑制自聚焦

讨论了由光束自聚焦引起的细丝形成和光束分裂，为了克服聚焦造成的破坏要求在光束传播中采用中继成像和空间滤波。     

砼受压损伤力学本构模型的研究

本文利用ＭＴＳ公司８１５．０２型电液伺服试验系统对砼进行了等应变速率加载控制的应力一应变全曲线试验，应用不可逆热力学和内变量理论的成果建立了砼损伤力学模型，并用概率统计的观点分析了损伤的演化规律。由于考虑了不可逆变形的影响，本文所建本构模型与实验吻合较好。     

LOW-CYCLE FATIGUE UNDER NON-PROPORTIONAL LOADING

A series of strain-controlled, low-cycle fatigue experiments have been conducted on 42CrMo steel under various loading paths including circular, square, cruciform, and rectangular paths. Present experiments have shown that there is additional hardening under non-proportional cyclic loading. Non-proportional cyclic additional hardening also results in a shorter life for multiaxial low cycle fatigue. A non-proportionality measure of strain path based on both a physical basis and macromechanical phenomena is proposed. The loading path effect on additional hardening is also described well. Low-cycle fatigue damage accumulation and the evolution process under non-proportional loading is analysed via the Continuum Damage Mechanics Model of Chaboche. A non-proportinality measure is introduced in the damage evolution equation and a modified Coffin-Manson type formula is derived. A novel fatigue life prediction approach based on the critical-plane concept of Brown and Miller is proposed.     

东海西湖凹陷探井钻井完井液技术

介绍了东海西湖凹陷的储层特征。在分析探井储层损害原因的基础上，提出了优化的海水钻井完井液体系。两口井应用表明，储层保护效果明显。     

PbO－Bi_2O_3－B_2O_3－SiO_2系重金属氧化物玻璃的结构与光学性

通过密度、可见光光谱、红外吸收光谱、Ｃｏ－６０辐照损伤试验及荧光光谱的测试，研究了ＰｂＯ－Ｂｉ２Ｏ３－Ｂ２Ｏ３－ＳｉＯ２玻璃系的光学性能与结构．密度最高可达８．４６４ｇ／ｃｍ３其紫外吸收达截止波长随Ｐｂ２＋及Ｂｉ３＋含量升高而红移．玻璃熔化温度低达８５０℃．在ＰｂＯ－Ｂｉ２Ｏ３－Ｂ２Ｏ３系玻璃中加人ＳｉＯ２可使玻璃结构更致密．室温下该系统玻璃在３６０ｎｍ有一个宽的激发峰，能产生４１８ｕｍ及４３８ｕｍ两个弱的发射峰．该系统玻璃的结构是由［ＳｉＯ４］４－、［ＢＯ３］３－、［ＢＯ４］５－、［ＰｂＯ４］６－及［ＢｉＯ６］９－构成．其中部分Ｐｂ２＋及Ｂｉ３＋以网络外体进入玻璃．     

The electron microscopy of post-growth induced defects of ZnSe/GaAs epilayers

A fundamental research of structural defects induced upon post-growth processing of ZnSe/GaAs epilayers grown on (100) GaAs was done by identifying defect-related reflections in the transmission electron diffraction (TED) patterns of ZnSe. Structural artifacts, other than the as-grown defects, on this material system could be excluded according to our results. Four types of abnormal reflections have been observed in addition to primary reflections. These extra reflections are sensitive to the post-growth processing of ZnSe epilayers and may arise from various external effects, rather than epitaxy growth, such as irradiation damage, surface oxidation, and surface contamination. By mapping these reflections at several major zone axes using TED patterns, we found that the reciprocal lattice for a ZnSe crystal with structural defects consists of two distinct types of extra reflections associated with irradiation damage. The first type of extra reflections is ±1/3{111} and the other is ±1/2{111} corresponding to pure-edge and non-edge dislocation loops, respectively. For (100) oriented wafers, the ±1/3{111} and ±1/2{111} reflections were observed only on two of the four possible 〈111〉 variants (i.e. [111]_Zn and [111]_Zn)and this phenomenon was attributed to the anisotropy of defect distribution. Extra reflections associated with surface oxidation and contamination are also observed. The orientation relationships between a surface hexagonal ZnO and a cubic ZnSe film are [0001]_ZnO//[−111]_ZnSe, and [01−11]_ZnO//[011]_ZnSe. The origin, characterization, and elimination of these induced reflections are discussed. With the knowledge about these extra effects on structural defect formation, we have shown the real microstructure of ZnSe epilayers.     

激光对望远系统损伤的研究

本文对激光光束通过望远系统后光束的变化进行了分析，并对６倍望远镜进行了激光损伤和破坏的实验研究，实验结果表明，激光对望远系统的损伤破坏主要是热效应所致，损伤破坏的情况与激光的能量，波长，脉冲宽度和望远系统的结构有关。     

上海市吴淞工业区大气PM2.5水溶成分的元素分析及细胞毒性研究

通过ICP-MS测定了上海市吴淞地区大气PM2.5水溶成分金属元素含量,通过四唑盐(MTT)测定细胞存活率,通过超氧化歧化酶(SOD)和丙二醛(MDA)两个指标测定细胞氧化损伤,琼脂糖凝胶电泳测定细胞内DNA损伤,流式细胞仪(Flow cytometry)检测细胞凋亡和周期等实验研究了大气PM2.5水溶成分的细胞毒性.实验结果表明:PM2.5可溶成分中Zn元素含量最高,PM2.5在一定浓度范围内能导致细胞死亡,引起细胞的氧化损伤,影响DNA的复制,阻碍细胞增殖,但没有诱导细胞凋亡.PM2.5中可溶金属离子对细胞毒性表现为联合作用.